Researchers at Rensselaer Polytechnic Institute have discovered and demonstrated a new method for overcoming two major hurdles facing solar energy. By developing a new antireflective coating that boosts the amount of sunlight captured by solar panels and allows those panels to absorb the entire solar spectrum from nearly any angle.
To get maximum efficiency when converting solar power into electricity, every single of photon of light should be absorbed by solar panel regardless of the sun’s position of the sky. New antireflective coating synthesized by the researchers makes it possible.
An untreated silicon solar cell only absorbs 67.4 percent of sunlight shone upon it — meaning that nearly one-third of that sunlight is reflected away and thus unharvestable. From an economic and efficiency perspective, this unharvested light is wasted potential and a major barrier hampering the proliferation and widespread adoption of solar power.
After a silicon surface was treated with new nano engineered reflective coating, however, the material absorbed 96.21 percent of sunlight shone upon it — meaning that only 3.79 percent of the sunlight was reflected and misutilised. This huge gain in absorption was consistent across the entire spectrum of sunlight, from UV to visible light and infrared, and moves solar power a significant step forward toward economic viability.
Typical antireflective coatings are engineered to transmit light of one particular wavelength. This new coating stacks seven of these layers, one on top of the other, in such a way that each layer enhances the antireflective properties of the layer below it. These additional layers also help to bend the flow of sunlight to an angle that augments the coating's antireflective properties. This means that each layer not only transmits sunlight, it also helps to capture any light that may have otherwise been reflected off of the layers below it.
The seven layers, each with a height of 50 nanometers to 100 nanometers, are made up of silicon dioxide and titanium dioxide nanorods positioned at an oblique angle — each layer looks and functions similar to a dense forest where sunlight is "captured" between the trees. The nanorods were attached to a silicon substrate via chemical vapor disposition.
The added advantage is that the new coating can be affixed to nearly any photovoltaic materials for use in solar cells, including III-V multi-junction and cadmium telluride.
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